ipso-Nitration of Arylboronic Acids with Bismuth Nitrate and Perdisulfate
Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai, 400076, India
Org. Lett., 2012, 14 (7), pp 1736–1739
DOI: 10.1021/ol300325t
Publication Date (Web): March 12, 2012
Copyright © 2012 American Chemical Society
Abstract
An efficient and one pot synthetic method of ipso-nitration of arylboronic acids has been developed. The high efficiency, general applicability, and broader substrate scope including heterocycles and functional groups make this method advantageous. Due to its simplicity, we expect to find application of this method in synthesis.
Supporting Information
Experimental procedures and characterization data for all new and known compounds. This material is available free of charge via the Internet at http://pubs.acs.org.
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