Single-Electron Transmetalation:
An Enabling Technology for Secondary Alkylboron Cross-Coupling
† Roy and Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104-6323, United States
‡ Department of Chemistry, Faculty of Sciences and Letters, Osmaniye Korkut Ata University, 80000 Osmaniye, Turkey
J. Am. Chem. Soc., 2015, 137 (6), pp 2195–2198
DOI: 10.1021/ja512946e
Publication Date (Web): February 4, 2015
Copyright © 2015 American Chemical Society
Note
Reference 16 was replaced February 9, 2015.
Abstract
Single-electron-mediated alkyl transfer affords a novel mechanism for transmetalation, enabling cross-coupling under mild conditions. Here, general conditions are reported for cross-coupling of secondary alkyltrifluoroborates with an array of aryl bromides mediated by an Ir photoredox catalyst and a Ni cross-coupling catalyst.
Experimental details and spectral data. This material is available free of charge via the Internet at http://pubs.acs.org.
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